Preheat your oven to 400°F (200°C).
Pat the pork chops dry with paper towels. This helps them brown, not steam.
Mix together the brown sugar, garlic, paprika, salt, and pepper in a small bowl.
Rub the seasoning mix all over the pork chops—get in there, don’t be shy.
Heat the olive oil in an oven-safe skillet over medium-high heat.
Sear the pork chops for 2-3 minutes per side until they get a nice golden crust.
Transfer the skillet to the oven and bake for 10-12 minutes or until the chops reach 145°F (63°C).
Let them rest for 5 minutes before serving—yes, really, it’s worth the wait.